Title

Reactions Of 1,3-Dibromo-1,1-Difluoro Compounds With 1,8-Diazabicyclo 5.4.0 Undec-7-Ene

Authors

Authors

S. Elsheimer; C. J. Foti;M. D. Bartberger

Comments

Authors: contact us about adding a copy of your work at STARS@ucf.edu

Abbreviated Journal Title

J. Org. Chem.

Keywords

Chemistry, Organic

Abstract

Difluorodienes result from the double dehydrobromination of 4-aryl-1,3-dibromo-1,1-difluorobutanes with DBU. Attempted syntheses of analogous 4-alkyl or C-alkoxy dienes yield monoelimination products under mild conditions and unexpected trifluoro compounds under more vigorous conditions. 4-Aryl-1,1-difluoro-1,3-butadienes react rapidly with 4-phenyl-1,2,4-triazoline-3,5-dione in Diels-Alder reactions, but these dienes are unreactive toward several other electron-deficient and electron-rich dienophiles.

Journal Title

Journal of Organic Chemistry

Volume

61

Issue/Number

18

Publication Date

1-1-1996

Document Type

Article

DOI Link

http://dx.doi.org/10.1021/jo960992k

Language

English

First Page

6252

Last Page

6255

WOS Identifier

WOS:A1996VG14400031

ISSN

0022-3263

Recommended Citation

"Reactions Of 1,3-Dibromo-1,1-Difluoro Compounds With 1,8-Diazabicyclo 5.4.0 Undec-7-Ene" (1996). Faculty Bibliography 1990s. 1617.
https://stars.library.ucf.edu/facultybib1990/1617