Title

Methylated mercury species in municipal waste landfill gas sampled in Florida, USA

Authors

Authors

S. E. Lindberg; D. Wallschlager; E. M. Prestbo; N. S. Bloom; J. Price;D. Reinhart

Comments

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Abbreviated Journal Title

Atmos. Environ.

Keywords

METHYLMERCURY; MECHANISMS; DEPOSITION; Environmental Sciences; Meteorology & Atmospheric Sciences

Abstract

Mercury-bearing material has been placed in municipal landfills from a wide array of sources including fluorescent lights, batteries, electrical switches, thermometers, and general waste. Despite its known volatility, persistence, and toxicity in the environment, the fate of mercury in landfills has not been widely studied. The nature of landfills designed to reduce waste through generation of methane by anaerobic bacteria suggests the possibility that these systems might also serve as bioreactors for the production of methylated mercury compounds. The toxicity of such species mandates the need to determine if they are emitted in municipal landfill gas (LFG). In a previous study, we had measured levels of total gaseous mercury (TGM) in LFG in the mug/m(3) range in two Florida landfills, and elevated levels of monomethyl mercury (MMM) were identified in LFG condensate, suggesting the possible existence of gaseous organic Hg compounds in LFG. In the current study, we measured TGM, Hg-0, and methylated mercury compounds directly in LFG from another Florida landfill. Again, TGM was in the mug/m(3) range, MMM was found in condensate, and this time we positively identified dimethyl mercury (DMM) in the LGF in the mug/m(3) range. These results identify landfills as a possible anthropogenic source of DMM emissions to air, and may help explain the reports of MMM in continental rainfall. Published by Elsevier Science Ltd.

Journal Title

Atmospheric Environment

Volume

35

Issue/Number

23

Publication Date

1-1-2001

Document Type

Article

Language

English

First Page

4011

Last Page

4015

WOS Identifier

WOS:000170437000010

ISSN

1352-2310

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