Title

Superhydrophobic mats of polymer-derived ceramic fibers

Authors

Authors

S. Sarkar; A. Chunder; W. F. Fei; L. N. An;L. Zhai

Comments

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Abbreviated Journal Title

J. Am. Ceram. Soc.

Keywords

SILICON-BASED CERAMICS; EXHIBITING SUPERHYDROPHOBICITY; SILICOALUMINUM; CARBONITRIDE; SURFACES; LOTUS; FILMS; NANOFIBERS; CONVERSION; PRECURSOR; FABRICS; Materials Science, Ceramics

Abstract

Solid preceramic polyaluminasilazane was synthesized through the reaction between liquid cyclosilazane and aluminum tri-sec-butoxide at 160 degrees C. Electrospinning of polyaluminasilazane/polyethyleneoxide (1/0.0001 mass ratio) in chloroform solutions generated smooth fibers while the electrospun fibers from the chloroform/N,N-dimethylformamide solutions had submicrometer structures on the fiber surfaces. Smooth and rough SiCNO ceramic fibers were obtained by the pyrolysis of the green fibers with an 80% yield. Superhydrophobic mats of ceramic fibers were fabricated via a chemical vapor deposition of perfluorosilane onto the rough fibers. These superhydrophobic mats possess good chemical and thermal stability.

Journal Title

Journal of the American Ceramic Society

Volume

91

Issue/Number

8

Publication Date

1-1-2008

Document Type

Article

Language

English

First Page

2751

Last Page

2755

WOS Identifier

WOS:000258379300054

ISSN

0002-7820

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