Title

Self-assembled carbon-silicon carbonitride nanocomposites: highperformance anode materials for lithium-ion batteries

Authors

Authors

Y. Chen; C. Li; Y. G. Wang; Q. Zhang; C. Y. Xu; B. Q. Wei;L. N. An

Comments

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Abbreviated Journal Title

J. Mater. Chem.

Keywords

ELECTRODE MATERIALS; GRAPHITE; POLYMER; CERAMICS; STORAGE; Chemistry, Physical; Materials Science, Multidisciplinary

Abstract

A new class of nanocomposites comprising an amorphous silicon carbonitride matrix and carbon nanoclusters was synthesized by decomposing polymeric precursors with thermally induced phase separation. Electrochemical measurements show that the nanocomposite with 30% of carbon nanoclusters exhibits a specific capacity of 480 mA h g(-1) and excellent cycling performance. The high capacity of the nanocomposites is attributed to the formation of a novel structure around the SiCN-C interface. The excellent electrochemical properties, together with the simple, low-cost processing, make the nanocomposites very promising for Li-ion battery applications.

Journal Title

Journal of Materials Chemistry

Volume

21

Issue/Number

45

Publication Date

1-1-2011

Document Type

Article

Language

English

First Page

18186

Last Page

18190

WOS Identifier

WOS:000296735900007

ISSN

0959-9428

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