Title

Cationic Mn-4 Single-Molecule Magnet with a Sterically Isolated Core

Authors

Authors

K. J. Heroux; H. M. Quddusi; J. Liu; J. R. O'Brien; M. Nakano; E. del Barco; S. Hill;D. N. Hendrickson

Comments

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Abbreviated Journal Title

Inorg. Chem.

Keywords

GROUND-STATE; MIXED-VALENT; PARAMETERS; COMPLEXES; CLUSTER; ION; Chemistry, Inorganic & Nuclear

Abstract

The synthesis, structure, and magnetic properties of a ligand-modified Mn-4 dicubane single-molecule magnet (SMM), [Mn-4(Bet)(4)(mdea)(2)(mdeaH)(2)] (BPh4)(4), are presented, where the cationic SMM units are significantly separated from neighboring molecules in the crystal lattice. There are no cocrystallized solvate molecules, making it an ideal candidate for single-crystal magnetization hysteresis and high-frequency electron paramagnetic resonance studies. Increased control over intermolecular interactions in such materials is a crucial factor in the future application of SMMs.

Journal Title

Inorganic Chemistry

Volume

50

Issue/Number

16

Publication Date

1-1-2011

Document Type

Article

DOI Link

http://dx.doi.org/10.1021/ic201017r

Language

English

First Page

7367

Last Page

7369

WOS Identifier

WOS:000293493100003

ISSN

0020-1669

Recommended Citation

"Cationic Mn-4 Single-Molecule Magnet with a Sterically Isolated Core" (2011). Faculty Bibliography 2010s. 1384.
https://stars.library.ucf.edu/facultybib2010/1384