Title

Properties of an Infrared-Transparent MgO:Y2O3 Nanocomposite

Authors

Authors

D. C. Harris; L. R. Cambrea; L. F. Johnson; R. T. Seaver; M. Baronowski; R. Gentilman; C. Nordahl; T. Gattuso; S. Silberstein; P. Rogan; T. Hartnett; B. Zelinski; W. Sunne; E. Fest; W. H. Poisl; C. B. Willingham; G. Turri; C. Warren; M. Bass; D. E. Zelmon;S. M. Goodrich

Comments

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Abbreviated Journal Title

J. Am. Ceram. Soc.

Keywords

SINGLE-CRYSTAL MGO; CERAMIC NANOCOMPOSITES; MAGNESIUM-OXIDE; THERMODYNAMIC PROPERTIES; THERMAL-CONDUCTIVITY; ELASTIC PROPERTIES; OPTICAL-MATERIALS; TEMPERATURE; YTTRIA; MICROSTRUCTURE; Materials Science, Ceramics

Abstract

A 50:50vol% MgO-Y2O3 nanocomposite with similar to 150nm grain size was prepared in an attempt to make 3-5m infrared-transmitting windows with increased durability and thermal shock resistance. Flexure strength of the composite at 21 degrees C is 679MPa for 0.88cm(2) under load. Hardness is consistent with that of the constituents with similar grain size. For 3-mm-thick material at 4.85m, the total scatter loss is 1.5%, forward scatter is 0.2%, and absorptance is 1.8%. Optical scatter below 2m is 100%. Variable intensity OH absorption (similar to 6% absorptance) is observed near 3m. The refractive index is similar to 0.4% below the volume-fraction-weighted average of those of the constituents. Thermal expansion is equal to the volume-fraction-weighted average of expansion of the constituents. Specific heat capacity is equal to the mass-fraction-weighted average of heat capacities of the constituents. Thermal conductivity lies between those of the constituents up to 1200K. Elastic constants lie between those of the constituents. The Hasselman mild thermal shock resistance parameter for the composite is twice as great as that of common 3-5m window materials, but half as great as that of c-plane sapphire.

Journal Title

Journal of the American Ceramic Society

Volume

96

Issue/Number

12

Publication Date

1-1-2013

Document Type

Article

Language

English

First Page

3828

Last Page

3835

WOS Identifier

WOS:000328102100023

ISSN

0002-7820

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