Keywords

Amines, Organic compounds -- Synthesis

Abstract

This report discusses research concerning synthetic applications of enaminoketones. The work may be divided into four parts as follows: a) replacement of the dimethylamino group of certain enaminones by other amine groups through a simple procedure; b) formation of 3-alkyl-pyrazoles; c) formation of 2-amino-4-alkyl-pyrimidines; d) synthesis and subsequent reduction of iminium salts. The starting materials (E-1-(N,N-dimethylamino)-1-alkene-3-ones) have been condensed with hydrazine and guanidine to form pyrazoles and pyrimidines, respectively. The same starting materials have been reacted with POCl3 in CH2Cl2 to produce chlorovinyliminium salts. These have then been reacted in situ with reducing agents to produce chlorovinyl amines. Additionally, the experimental procedures used to produce these products are revealed, and the physical properties of the products are given. Recommendations for future research are made.

Notes

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Graduation Date

1986

Semester

Summer

Advisor

Gupton, John T.

Degree

Master of Science (M.S.)

College

College of Arts and Sciences

Department

Chemistry

Degree Program

Industrial Chemistry

Format

PDF

Pages

42 p.

Language

English

Rights

Public Domain

Length of Campus-only Access

None

Access Status

Masters Thesis (Open Access)

Identifier

DP0019593

Contributor (Linked data)

John T. Gupton (Q58389893)

Accessibility Status

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