Title

The Czochralski growth of large-diameter La3Ga5.5Ta0.5O14 crystals along different orientations

Authors

Authors

J. Luo; D. Shah; C. F. Klemenz; M. Dudley;H. Chen

Comments

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Abbreviated Journal Title

J. Cryst. Growth

Keywords

defects; Czochralski; LGT; piezoelectric material; resonators; PIEZOELECTRIC SINGLE-CRYSTALS; LANGASITE STRUCTURE; LA3GA5SIO14 LGS; Crystallography; Materials Science, Multidisciplinary; Physics, Applied

Abstract

La3Ga5SiO14, La3Ga5.5Ta0.5O14 and La3Ga5.5Nb0.5O14 crystals exhibit outstanding piezoelectric properties. They are of considerable interest for high-precision resonators. Although the synthesis of these crystals has been actively pursued over the past years, there are still some setbacks slowing down industrial applications. We report on the growth of La3Ga5.5Ta0.5O14 (LGT) crystals by the Czochralski growth along < 001 >, < 100 > and < 120 >. These crystals were characterized by different techniques, including X-ray synchrotron topography. LGT crystals show a facet structure which determines the overall 3D distribution of other defects and strain. The relationship between faceting and crystal imperfections such as striations, dislocations, and inclusions will be discussed. After optimization of growth conditions, inclusions-free, colorless transparent single crystals with a diameter of 2" were obtained. These crystals were processed into Y-cut plano-convex resonators, and the Qf product measured from fundamental to ninth overtone. Values exceeding the limit of AT- and SC-cut quartz were obtained. (c) 2005 Elsevier B.V. All rights reserved.

Journal Title

Journal of Crystal Growth

Volume

287

Issue/Number

2

Publication Date

1-1-2006

Document Type

Article; Proceedings Paper

Language

English

First Page

300

Last Page

304

WOS Identifier

WOS:000235071600019

ISSN

0022-0248

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