Title

Mechanisms For The Alkaline Hydrolysis Of Dibromodifluoromethane-Alkene Adducts To Α,Β-Unsaturated Carboxylates

Keywords

Dehydrobromination; Halomethane; Hydrolysis

Abstract

Alternative mechanisms for the title reactions are probed. The previously-reported pathway involving double dehydrobromination to a difluorodiene is operative in at least one case, but this route is specifically excluded for systems that cannot dehydrobrominate to dienes yet still yield carboxylates upon alkaline hydrolysis. Although SN2, SN1, SRN1, and monoelimination-addition processes appear formally possible, an SN2′ mechanism is implicated by studies on model compounds. © 2000 Elsevier Science S.A.

Publication Date

1-1-2000

Publication Title

Journal of Fluorine Chemistry

Volume

102

Issue

1-2

Number of Pages

3-9

Document Type

Article

Personal Identifier

scopus

DOI Link

https://doi.org/10.1016/S0022-1139(99)00232-8

Socpus ID

0042280728 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/0042280728

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