Abbreviated Journal Title
Phys. Rev. A
PHOTOELECTRON SPECTROMETRY; PHOTOABSORPTION SPECTRA; NATURAL WIDTHS; AUGER LINES; MONOCHROMATOR; CHLORINE; AR; Optics; Physics, Atomic, Molecular & Chemical
The 2p-- > ns,md excitation spectrum has been measured and calculated for the open-shell C1 atom. A satisfactory accord between experiment and theory was found. Rydberg series cannot be discerned for transitions leading to a 2p, 3p, n iota open-shell configuration. The 4s,3d manifolds are dominant, and the 2p-3p coupling is seen to be much stronger than the 3p-n iota coupling. Very narrow widths, 16 to 22 meV, for the 4s and 3d lines an observed. By contrast, only broad structures appear in the region of the highest excitations. [S1050-2947(99)50302-8].
Physical Review A
Caldwell, C. D.; Krause, M. O.; Cowman, R. D.; Menzel, A.; Whitfield, S. B.; Hallman, S.; Frigo, S. P.; and Severson, M. C., "Inner-shell photoexcitation in an open-shell atom: The Cl 2p -> ns,md spectrum as a case study" (1999). Faculty Bibliography 1990s. 2572.