Abbreviated Journal Title
Phys. Rev. A
Photoelectron Spectrometry; Photoabsorption Spectra; Natural Widths; Auger Lines; Monochromator; Chlorine; Ar; Optics; Physics; Atomic; Molecular & Chemical
The 2p-- > ns,md excitation spectrum has been measured and calculated for the open-shell C1 atom. A satisfactory accord between experiment and theory was found. Rydberg series cannot be discerned for transitions leading to a 2p, 3p, n iota open-shell configuration. The 4s,3d manifolds are dominant, and the 2p-3p coupling is seen to be much stronger than the 3p-n iota coupling. Very narrow widths, 16 to 22 meV, for the 4s and 3d lines an observed. By contrast, only broad structures appear in the region of the highest excitations.
Physical Review A
Caldwell, C. D.; Krause, M. O.; Cowman, R. D.; Menzel, A.; Whitfield, S. B.; Hallman, S.; Frigo, S. P.; and Severson, M. C., "Inner-shell photoexcitation in an open-shell atom: The Cl 2p -> ns,md spectrum as a case study" (1999). Faculty Bibliography 1990s. 2572.