Abbreviated Journal Title
J. Chem. Phys.
CYANINE DYE; OPTICAL-PROPERTIES; ABSORPTION; EXCITONS; FILMS; FLUORESCENCE; TEMPERATURE; DYNAMICS; CRYSTAL; SPECTRA; Physics, Atomic, Molecular & Chemical
Herein we report the experimental and theoretical study of the temperature dependence of a thiacarbocyanine dye in its monomer, H- and J-aggregates states. We demonstrate the ability to control the ratio of monomer, H- and/or J-aggregates with heat. We link such a control to the conformation dependence of the molecule. An alternative way to gain access to the dominating species without changing the concentration as a complete switching mechanism between all the present species is proposed. The results presented in this work lead to a better understanding of thiacarbocyanine dye's behavior.
Journal of Chemical Physics
Passier, Rémy; Ritchie, James P.; Toro, Carlos; Diaz, Carlos; Masunov, Artëm E.; Belfield, Kevin D.; and Hernandez, Florencio E., "Thermally controlled preferential molecular aggregation state in a thiacarbocyanine dye" (2010). Faculty Bibliography 2010s. 630.