Keywords

XPS, Calcium, Lanthanum, Sulfide, Ceramics, Metrology, IR, CLS LWIR

Abstract

Long wave infrared (LWIR) optics that transmit in the 8 to 14 m wavelength range and, additionally, can withstand severe physical and thermal stresses are needed for advanced remote sensing, guidance and communication-based applications. However, most non-oxide transparent LWIR optics do not have the wider transmission range, nor the hardness and resistance to thermal shock needed for extreme environments. Because of these limitations, research is circling back to a promising material, calcium lanthanum sulfide (CLS), that could meet LWIR needs for extreme environments.

In this thesis, we will demonstrate the abilities of x-ray photoelectron spectroscopy (XPS) as a technique for characterizing CLS powders and ceramics for elemental analysis, valence state and stoichiometry evaluation. Three preliminary studies were conducted - a binary metal sulfide evaluation of lanthanum sulfide (La2S3) and calcium sulfide (CaS), and a calibration curve of mixtures of the two binary metal sulfide powders from a known concentration matrix. Based on these results, a methodology was developed to evaluate CLS powder and ceramics via XPS. We showcase the power of XPS to reliably determine CLS stoichiometry, identify impurities and defects as related to the presence of carbon and oxygen during processing, and predict the bonding environment of sulfur which can lead to better quality CLS ceramics.

This thesis demonstrates the use of XPS as a potential characterization tool in CLS to identify contaminants, determine if stoichiometry is met, and identify the bonding environments to assist in processing improvements for producing higher-quality ceramics.

Completion Date

2023

Semester

Fall

Committee Chair

Banerjee, Parag

Degree

Master of Science in Materials Science and Engineering (M.S.M.S.E.)

College

College of Engineering and Computer Science

Department

Materials Science and Engineering

Degree Program

Materials Science and Engineering

Format

application/pdf

Identifier

DP0028016

URL

https://purls.library.ucf.edu/go/DP0028016

Language

English

Release Date

December 2023

Length of Campus-only Access

None

Access Status

Masters Thesis (Open Access)

Campus Location

Orlando (Main) Campus

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