Large Spin-State Changes in Isostructural Cyanate- and Azide-Bridged (Mn3Mn2II)-Mn-III Single-Molecule Magnets
Abbreviated Journal Title
CLUSTERS; INTERFERENCE; DISTORTION; Chemistry, Inorganic & Nuclear
We prepared three structurally related (Mn3Mn2II)-Mn-III complexes that possess S approximate to 1 - 11 spin ground states as a result of variations in the geometry and identity of mu(2)-eta(1):eta(1) bridging groups. These complexes function as single-molecule magnets yet demonstrate other interesting behavior such as quasi-classical magnetization hysteresis and comparable magnetization reversal barriers (U-eff).
"Large Spin-State Changes in Isostructural Cyanate- and Azide-Bridged (Mn3Mn2II)-Mn-III Single-Molecule Magnets" (2010). Faculty Bibliography 2010s. 149.