Title
Large Spin-State Changes in Isostructural Cyanate- and Azide-Bridged (Mn3Mn2II)-Mn-III Single-Molecule Magnets
Abbreviated Journal Title
Inorg. Chem.
Keywords
CLUSTERS; INTERFERENCE; DISTORTION; Chemistry, Inorganic & Nuclear
Abstract
We prepared three structurally related (Mn3Mn2II)-Mn-III complexes that possess S approximate to 1 - 11 spin ground states as a result of variations in the geometry and identity of mu(2)-eta(1):eta(1) bridging groups. These complexes function as single-molecule magnets yet demonstrate other interesting behavior such as quasi-classical magnetization hysteresis and comparable magnetization reversal barriers (U-eff).
Journal Title
Inorganic Chemistry
Volume
49
Issue/Number
4
Publication Date
1-1-2010
Document Type
Article
DOI Link
Language
English
First Page
1304
Last Page
1306
WOS Identifier
ISSN
0020-1669
Recommended Citation
"Large Spin-State Changes in Isostructural Cyanate- and Azide-Bridged (Mn3Mn2II)-Mn-III Single-Molecule Magnets" (2010). Faculty Bibliography 2010s. 149.
https://stars.library.ucf.edu/facultybib2010/149
Comments
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