Large Spin-State Changes in Isostructural Cyanate- and Azide-Bridged (Mn3Mn2II)-Mn-III Single-Molecule Magnets

    Authors

    P. L. Feng; C. J. Stephenson; A. Amjad; G. Ogawa; E. del Barco;D. N. Hendrickson

    Comments

    Authors: contact us about adding a copy of your work at [email protected]

    Abbreviated Journal Title

    Inorg. Chem.

    Keywords

    CLUSTERS; INTERFERENCE; DISTORTION; Chemistry, Inorganic & Nuclear

    Abstract

    We prepared three structurally related (Mn3Mn2II)-Mn-III complexes that possess S approximate to 1 - 11 spin ground states as a result of variations in the geometry and identity of mu(2)-eta(1):eta(1) bridging groups. These complexes function as single-molecule magnets yet demonstrate other interesting behavior such as quasi-classical magnetization hysteresis and comparable magnetization reversal barriers (U-eff).

    Journal Title

    Inorganic Chemistry

    Volume

    49

    Issue/Number

    4

    Publication Date

    1-1-2010

    Document Type

    Article

    Language

    English

    First Page

    1304

    Last Page

    1306

    WOS Identifier

    WOS:000274240700012

    ISSN

    0020-1669

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