Large Spin-State Changes in Isostructural Cyanate- and Azide-Bridged (Mn3Mn2II)-Mn-III Single-Molecule Magnets

Authors

Authors

P. L. Feng; C. J. Stephenson; A. Amjad; G. Ogawa; E. del Barco;D. N. Hendrickson

Comments

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Abbreviated Journal Title

Inorg. Chem.

Keywords

CLUSTERS; INTERFERENCE; DISTORTION; Chemistry, Inorganic & Nuclear

Abstract

We prepared three structurally related (Mn3Mn2II)-Mn-III complexes that possess S approximate to 1 - 11 spin ground states as a result of variations in the geometry and identity of mu(2)-eta(1):eta(1) bridging groups. These complexes function as single-molecule magnets yet demonstrate other interesting behavior such as quasi-classical magnetization hysteresis and comparable magnetization reversal barriers (U-eff).

Journal Title

Inorganic Chemistry

Volume

49

Issue/Number

4

Publication Date

1-1-2010

Document Type

Article

DOI Link

http://dx.doi.org/10.1021/ic902298y

Language

English

First Page

1304

Last Page

1306

WOS Identifier

WOS:000274240700012

ISSN

0020-1669

Recommended Citation

"Large Spin-State Changes in Isostructural Cyanate- and Azide-Bridged (Mn3Mn2II)-Mn-III Single-Molecule Magnets" (2010). Faculty Bibliography 2010s. 149.
https://stars.library.ucf.edu/facultybib2010/149