Gold-doped graphene: A highly stable and active electrocatalysts for the oxygen reduction reaction
Abbreviated Journal Title
J. Chem. Phys.
PLATINUM-MONOLAYER ELECTROCATALYSTS; HYDROGEN FUEL-CELLS; CARBON-MONOXIDE; SURFACE ALLOYS; METAL-SURFACES; NANOPARTICLES; PERFORMANCE; DISSOLUTION; CATALYSTS; HYBRIDS; Physics, Atomic, Molecular & Chemical
In addressing the growing need of renewable and sustainable energy resources, hydrogen-fuel-cells stand as one of the most promising routes to transform the current energy paradigm into one that integrally fulfills environmental sustainability. Nevertheless, accomplishing this technology at a large scale demands to surpass the efficiency and enhance the cost-effectiveness of platinum-based cathodes, which catalyze the oxygen reduction reaction (ORR). In this work, our first-principles calculations show that Au atoms incorporated into graphene di-vacancies form a highly stable and cost-effective electrocatalyst that is, at the same time, as or more (dependently of the dopant concentration) active toward ORR than the best-known Pt-based electrocatalysts. We reveal that partial passivation of defected-graphene by gold atoms reduces the reactivity of C dangling bonds and increases that of Au, thus optimizing them for catalyzing the ORR and yielding a system of high thermodynamic and electrochemical stabilities. We also demonstrate that the linear relation among the binding energies of the reaction intermediates assumed in computational high-throughput material screening does not hold, at least for this non-purely transition-metal material. We expect Au-doped graphene to finally overcome the cathode-related challenge hindering the realization of hydrogen-fuel cells as the leading means of powering transportation and portable devices. (C) 2015 AIP Publishing LLC.
Journal of Chemical Physics
"Gold-doped graphene: A highly stable and active electrocatalysts for the oxygen reduction reaction" (2015). Faculty Bibliography 2010s. 6812.