Abbreviated Journal Title
J. Vac. Sci. Technol. A
Keywords
Surface-Chemistry; Silicates; Zeolites; Esca; Xps; Biocells; Materials Science; Coatings & Films; Physics; Applied
Abstract
The present study continues our x-ray photoelectron spectroscopy (XPS) or electron spectroscopy for chemical analysis investigations of silicate systems, particularly those in contact with biological materials. In the present case, the investigations are extended to a detailed analysis for a wide variety of soil samples extracted from different locations around the world. The samples were selected from relatively pristine sites, pressed into wafers, and were examined without further modification. All of the materials were insulators and therefore analysis required extensive use of the electron flood gun. Careful XPS chemical shift assignments have been achieved for many silicate minerals. These have been exploited in the present study along with the detailed XPS analysis of organofunctional groups rendered by Beamson and Briggs. As a result, a fairly detailed simultaneous nondestructive description is provided of the surface of both the humus and silt components of these soil samples. Substantial variations in the composition are demonstrated and questions are raised about our classifications of fertility.
Journal Title
Journal of Vacuum Science & Technology A
Volume
17
Issue/Number
4
Publication Date
1-1-1999
Document Type
Article; Proceedings Paper
DOI Link
Language
English
First Page
1079
Last Page
1085
WOS Identifier
ISSN
0734-2101
Recommended Citation
Barr, T. L.; Hoppe, E. E.; Hardcastle, S.; and Seal, S., "X-ray photoelectron spectroscopy investigations of the chemistries of soils" (1999). Faculty Bibliography 1990s. 2546.
https://stars.library.ucf.edu/facultybib1990/2546
Comments
Authors: contact us about adding a copy of your work at STARS@ucf.edu