Title

Synthesis of secondary amines via N-(benzoyloxy)amines and organoboranes

Authors

Authors

O. Phanstiel; Q. X. Wang; D. H. Powell; M. P. Ospina;B. A. Leeson

Comments

Authors: contact us about adding a copy of your work at STARS@ucf.edu

Abbreviated Journal Title

J. Org. Chem.

Keywords

CONVENIENT SYNTHESIS; AMINATION; TRIALKYLBORANES; DIALKYLAMINES; Chemistry, Organic

Abstract

A variety of primary amines (R-NH2) were converted to their corresponding N-(benzoyloxy)amines (i.e., R-NHOCOPh) under biphasic conditions in excellent yields (63-90%). The intermediate N-(benzoyloxy)amines were converted to their N-ethylamine derivatives upon reaction with triethylborane in THF in good yield (54-89%). These experiments demonstrated the similar chemistry of N-chloro- and N-(benzoyloxy)amines with organoboranes.

Journal Title

Journal of Organic Chemistry

Volume

64

Issue/Number

3

Publication Date

1-1-1999

Document Type

Article

Language

English

First Page

803

Last Page

806

WOS Identifier

WOS:000078548200026

ISSN

0022-3263

Share

COinS