Title

Effect of nanocrystallite morphology on the metastable tetragonal phase stabilization in zirconia

Authors

Authors

S. Shukla; S. Seal; R. Vij; S. Bandyopadhyay;Z. Rahman

Abbreviated Journal Title

Nano Lett.

Keywords

Chemistry, Multidisciplinary; Chemistry, Physical; Nanoscience &; Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter

Abstract

We synthesize, for the first time, using sol-gel technique and without doping any trivalent impurities, monodispersed, spherical ZrO2 particles in size range of similar to500-600 nm, exhibiting metastable tetragonal crystal structure at room temperature. It is revealed using high-resolution transmission electron microscopy that "hard-aggregates" forming tendency of ZrO2 nanocrystallites of size similar to45 nm is responsible for stabilizing the high-temperature metastable tetragonal phase, at room temperature, within large sized (similar to500-600 nm) undoped ZrO2 particles.

Journal Title

Nano Letters

Volume

2

Issue/Number

9

Publication Date

1-1-2002

Document Type

Article

Language

English

First Page

989

Last Page

993

WOS Identifier

WOS:000178010900017

ISSN

1530-6984

Share

COinS