Title

Growth and optical properties of ultra-long single-crystalline alpha-Si3N4 nanobelts

Authors

Authors

W. Yang; L. Zhang; Z. Xie; J. Li; H. Miao;L. An

Comments

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Abbreviated Journal Title

Appl. Phys. A-Mater. Sci. Process.

Keywords

SILICON-NITRIDE; THIN-FILMS; PHOTOLUMINESCENCE; NANOWIRES; SI; OXYNITRIDE; CERAMICS; NANORODS; SI3N4; Materials Science, Multidisciplinary; Physics, Applied

Abstract

Ultra-long single-crystalline alpha-Si3N4 nanobelts were synthesized by catalyst-assisted crystallization of polymer-derived amorphous silicon carbonitride (SiCN). The obtained nanobelts were characterized using X-ray diffraction, scanning electron microscopy, high-resolution transmission electron microscopy and selected-area electron diffraction. The results revealed that the alpha-Si3N4 nanobelts are 20 to 40 nm in thickness, 400 - 600 nm in width and a few hundreds of micrometers to several millimeters in length, and grow along either the [ 011] or the [ 100] direction. Intense visible photoluminescence was observed over a spectrum ranging from 1.65 to 3.01 eV, which can be attributed to defects in the alpha-Si3N4 structure.

Journal Title

Applied Physics a-Materials Science & Processing

Volume

80

Issue/Number

7

Publication Date

1-1-2005

Document Type

Article

Language

English

First Page

1419

Last Page

1423

WOS Identifier

WOS:000227908400007

ISSN

0947-8396

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