The Czochralski growth of large-diameter La3Ga5.5Ta0.5O14 crystals along different orientations

Authors

    Authors

    J. Luo; D. Shah; C. F. Klemenz; M. Dudley;H. Chen

    Comments

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    Abbreviated Journal Title

    J. Cryst. Growth

    Keywords

    defects; Czochralski; LGT; piezoelectric material; resonators; PIEZOELECTRIC SINGLE-CRYSTALS; LANGASITE STRUCTURE; LA3GA5SIO14 LGS; Crystallography; Materials Science, Multidisciplinary; Physics, Applied

    Abstract

    La3Ga5SiO14, La3Ga5.5Ta0.5O14 and La3Ga5.5Nb0.5O14 crystals exhibit outstanding piezoelectric properties. They are of considerable interest for high-precision resonators. Although the synthesis of these crystals has been actively pursued over the past years, there are still some setbacks slowing down industrial applications. We report on the growth of La3Ga5.5Ta0.5O14 (LGT) crystals by the Czochralski growth along < 001 >, < 100 > and < 120 >. These crystals were characterized by different techniques, including X-ray synchrotron topography. LGT crystals show a facet structure which determines the overall 3D distribution of other defects and strain. The relationship between faceting and crystal imperfections such as striations, dislocations, and inclusions will be discussed. After optimization of growth conditions, inclusions-free, colorless transparent single crystals with a diameter of 2" were obtained. These crystals were processed into Y-cut plano-convex resonators, and the Qf product measured from fundamental to ninth overtone. Values exceeding the limit of AT- and SC-cut quartz were obtained. (c) 2005 Elsevier B.V. All rights reserved.

    Journal Title

    Journal of Crystal Growth

    Volume

    287

    Issue/Number

    2

    Publication Date

    1-1-2006

    Document Type

    Article; Proceedings Paper

    Language

    English

    First Page

    300

    Last Page

    304

    WOS Identifier

    WOS:000235071600019

    ISSN

    0022-0248

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