Microstructure and residual stress of alumina scale formed on Ti2AlC at high temperature in air

    Authors

    J. W. Byeon; J. Liu; M. Hopkins; W. Fischer; N. Garimella; K. B. Park; M. P. Brady; M. Radovic; T. El-Raghy;Y. H. Sohn

    Comments

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    Abbreviated Journal Title

    Oxid. Met.

    Keywords

    Ti2AlC; coefficient of thermal expansion; ternary carbide; oxidation; residual stress; photoluminescence spectroscopy; transmission electron; microscopy; LIQUID REACTION SYNTHESIS; OXIDATION BEHAVIOR; PHASE-TRANSFORMATIONS; GROWTH STRESS; OXIDE SCALE; TI3SIC2; CERAMICS; TI3ALC2; CARBIDE; STRAIN; Metallurgy & Metallurgical Engineering

    Abstract

    Ti2AlC ternary carbide is being explored for various high temperature applications due to its strength at high temperatures, excellent thermal-shock resistance, and high electrical conductivity. A potential advantage of Ti2AlC over conventional Al2O3-forming materials is the near-identical coefficient of thermal expansion (CTE) of Ti2AlC and alpha-Al2O3, which could result in superior spallation resistance and make Ti2AlC a promising option for applications ranging from bondcoats for thermal barrier coatings to furnace heating elements. In this study, isothermal and cyclic oxidation were performed in air to examine the oxidation behavior of Ti2AlC. Isothermal oxidation was performed at 1000, 1200 and 1400 degrees C for up to 25 h and cyclic oxidation consisted of 1,000 1-hour cycles at 1200 degrees C. Characteristics of the oxide scale developed in air, including mass change, residual stress in the alpha-Al2O3 scale, phase constituents and microstructure, were examined as functions of time and temperature by thermogravimetry, photostimulated luminescence, x-ray diffraction, scanning electron microscopy, and transmission electron microscopy via focused ion beam in situ lift-out. Above a continuous and adherent alpha-Al2O3 layer, a discontinuous-transient rutile-TiO2 scale was identified in the oxide scale developed at 1000 and 1200 degrees C, while a discontinuous-transient Al2TiO5 scale was identified at 1400 degrees C. The continuous alpha-Al(2)O(3)scale thickened to more than 15 mu m after 25 h of isothermal oxidation at 1400 degrees C, and after 1,000 1-hour cycles at 1200 degrees C, yet remained adherent and protective. The compressive residual stress determined by photoluminescence for the alpha-Al2O3 scale remained under 0.65 GPa for the specimens oxidized up to 1400 degrees C for 25 hours. The small magnitude of the compressive residual stress may be responsible the high spallation-resistance of the protective alpha-Al2O3 scale developed on Ti2AlC, despite the absence of reactive element additions.

    Journal Title

    Oxidation of Metals

    Volume

    68

    Issue/Number

    1-2

    Publication Date

    1-1-2007

    Document Type

    Article

    Language

    English

    First Page

    97

    Last Page

    111

    WOS Identifier

    WOS:000247931600008

    ISSN

    0030-770X

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