Metalloporphyrin nanotube fabrication using peptide nanotubes as templates

Authors

    Authors

    H. Matsui;R. MacCuspie

    Comments

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    Abbreviated Journal Title

    Nano Lett.

    Keywords

    MOLECULAR RECOGNITION; ELECTRONIC-PROPERTIES; CHEMICAL SENSORS; CARBON; NANOTUBES; FIELD EMITTERS; ARRAYS; FILMS; MONOLAYERS; SIEVES; WIRES; Chemistry, Multidisciplinary; Chemistry, Physical; Nanoscience &; Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter

    Abstract

    Protoporphyrin IX Zn(ll) has been demonstrated to form metalloporphyrin coatings on peptide nanotubes via hydrogen bonds and produce metalloporphyrin nanotubes. This diacid metalloporphyrin was stabilized on the peptide nanotube surfaces with two types of hydrogen bonds, intermolecular hydrogen bond between the carboxylic acid of metalloporphyrins and the amide of peptide nanotube and intermolecular hydrogen bond between the carboxylic acids of neighboring metalloporphyrins. Since previous study indicates that the peptide nanotubes can potentially be assembled as arrays, the applications of metalloporphyrin nanotubes to nanoscale chemical sensors or photonics may be possible.

    Journal Title

    Nano Letters

    Volume

    1

    Issue/Number

    12

    Publication Date

    1-1-2001

    Document Type

    Article

    Language

    English

    First Page

    671

    Last Page

    675

    WOS Identifier

    WOS:000174078000001

    ISSN

    1530-6984

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