Title
Chip-scale Mid- Infrared chemical sensors using air-clad pedestal silicon waveguides
Abbreviated Journal Title
Lab Chip
Keywords
SURFACE-PLASMON RESONANCE; BIOLOGICAL ANALYSIS; OPTICAL SENSORS; SPECTROSCOPY; FILM; Biochemical Research Methods; Chemistry, Multidisciplinary; Nanoscience; & Nanotechnology
Abstract
Towards a future lab-on-a-chip spectrometer, we demonstrate a compact chip-scale air-clad silicon pedestal waveguide as a Mid-Infrared (Mid-IR) sensor capable of in situ monitoring of organic solvents. The sensor is a planar crystalline silicon waveguide, which is highly transparent, between lambda = 1.3 and 6.5 mu m, so that its operational spectral range covers most characteristic chemical absorption bands due to bonds such as C-H, N-H, O-H, C-C, N-O, C=O, and C=N, as opposed to conventional UV, Vis, Near-IR sensors, which use weaker overtones of these fundamental bands. To extend light transmission beyond lambda = 3.7 mu m, a spectral region where a typical silicon dioxide under-clad is absorbing, we fabricate a unique air-clad silicon pedestal waveguide. The sensing mechanism of our Mid-IR waveguide sensor is based on evanescent wave absorption by functional groups of the surrounding chemical molecules, which selectively absorb specific wavelengths in the mid-IR, depending on the nature of their chemical bonds. From a measurement of the waveguide mode intensities, we demonstrate in situ identification of chemical compositions and concentrations of organic solvents. For instance, we show that when testing at lambda = 3.55 mu m, the Mid-IR sensor can distinguish hexane from the rest of the tested analytes (methanol, toluene, carbon tetrachloride, ethanol and acetone), since hexane has a strong absorption from the aliphatic C-H stretch at l = 3.55 mu m. Analogously, applying the same technique at lambda = 3.3 mm, the Mid-IR sensor is able to determine the concentration of toluene dissolved in carbon tetrachloride, because toluene has a strong absorption at lambda = 3.3 mm from the aromatic C-H stretch. With our demonstration of an air-clad silicon pedestal waveguide sensor, we move closer towards the ultimate goal of an ultra-compact portable spectrometer-on-a-chip.
Journal Title
Lab on a Chip
Volume
13
Issue/Number
11
Publication Date
1-1-2013
Document Type
Article
DOI Link
Language
English
First Page
2161
Last Page
2166
WOS Identifier
ISSN
1473-0197
Recommended Citation
"Chip-scale Mid- Infrared chemical sensors using air-clad pedestal silicon waveguides" (2013). Faculty Bibliography 2010s. 4312.
https://stars.library.ucf.edu/facultybib2010/4312
Comments
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