Title

Water-Stable Manganese(IV) Complex of a N2O4-Donor Non-Schiff-Base Ligand: Synthesis, Structure, and Multifrequency High-Field Electron Paramagnetic Resonance Studies

Authors

Authors

M. Dolai; A. Amjad; M. Debnath; J. van Tol; E. del Barco;M. Ali

Comments

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Abbreviated Journal Title

Inorg. Chem.

Keywords

LACTOBACILLUS-PLANTARUM; VALENCE TAUTOMERISM; OXIDATION; CLUSTER; CHEMISTRY; SYSTEM; SERIES; OXYGEN; ION; Chemistry, Inorganic & Nuclear

Abstract

A novel water-stable (t(1/2) similar to 6.8 days) mononuclear manganese(IV) complex of a hexacoordinating non-Schiff-base ligand (H4L) with N2O4-donor atoms has been synthesized and characterized crystallographically. High-frequency electron paramagnetic resonance experiments performed on a single crystal reveal a manganese(IV) ion with an S = 3/2 ground spin state that displays a large single-ion anisotropy, setting the record of mononuclear manganese(IV) complexes reported so far. In addition, spin-echo experiments reveal a spin-spin relaxation time T-2 similar to 500 ns.

Journal Title

Inorganic Chemistry

Volume

53

Issue/Number

11

Publication Date

1-1-2014

Document Type

Article

DOI Link

http://dx.doi.org/10.1021/ic4030958

Language

English

First Page

5423

Last Page

5428

WOS Identifier

WOS:000336942500007

ISSN

0020-1669

Recommended Citation

"Water-Stable Manganese(IV) Complex of a N2O4-Donor Non-Schiff-Base Ligand: Synthesis, Structure, and Multifrequency High-Field Electron Paramagnetic Resonance Studies" (2014). Faculty Bibliography 2010s. 5265.
https://stars.library.ucf.edu/facultybib2010/5265