Title
Comparison of shaking versus baking: further understanding the energetics of a mechanochemical reaction
Abbreviated Journal Title
Green Chem.
Keywords
DISCRETE ELEMENT METHOD; DIELS-ALDER REACTIONS; DENSITY-FUNCTIONAL; THEORY; TUMBLING MILLS; FULLERENE C-60; BALL MILLS; SIMULATION; PREDICTION; SHAKER; C-120; Chemistry, Multidisciplinary
Abstract
Using a mechanically driven Diels-Alder reaction we were able to characterize the chemical energetics of a SPEX 8000M mixer/mill. Our results demonstrate that the conditions produced by this type of mill are similar to those produced when performing the same reaction at 90 degrees C in solution. Discrete element models and in situ temperature logging were used to analyse the energetics of this system. These models indicate that the yields obtained using a SPEX 8000M mill are best correlated to the velocity of the media and number of non-zero force collisions.
Journal Title
Green Chemistry
Volume
16
Issue/Number
3
Publication Date
1-1-2014
Document Type
Article
DOI Link
Language
English
First Page
1628
Last Page
1632
WOS Identifier
ISSN
1463-9262
Recommended Citation
"Comparison of shaking versus baking: further understanding the energetics of a mechanochemical reaction" (2014). Faculty Bibliography 2010s. 5825.
https://stars.library.ucf.edu/facultybib2010/5825
Comments
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