Title

Fabrication of layered Ti3C2 with an accordion-like structure as a potential cathode material for high performance lithium-sulfur batteries

Authors

Authors

X. Q. Zhao; M. Liu; Y. Chen; B. Hou; N. Zhang; B. B. Chen; N. Yang; K. Chen; J. L. Li;L. A. An

Comments

Authors: contact us about adding a copy of your work at STARS@ucf.edu

Abbreviated Journal Title

J. Mater. Chem. A

Keywords

HIGH SPECIFIC ENERGY; ION BATTERIES; OXYGEN REDUCTION; ANODE MATERIALS; HIGH-CAPACITY; CARBON; COMPOSITES; TI3ALC2; NANOPLATELETS; EXFOLIATION; Chemistry, Physical; Energy & Fuels; Materials Science, ; Multidisciplinary

Abstract

In order to enhance the long-term stability of sulfur cathodes used in rechargeable high energy lithium-sulfur (Li-S) batteries, layered Ti3C2 (L-Ti3C2) with an accordion-like structure was prepared by exfoliating Ti3AlC2 in 40% hydrofluoric acid. The L-Ti3C2 was then loaded with sulfur (57.6 wt%) to form a S/L-Ti3C2 composite. The composite was then used as a cathode material for Li-S batteries, which showed a high initial discharge capacity of 1291 mA h g(-1) and an excellent capacity retention of 970 mA h g(-1) after 100 cycles. The results suggest that two-dimensional carbides, similar to graphene and/or graphite, are a promising material for a wide range of applications in Li-S batteries and other electrochemical energy storage devices.

Journal Title

Journal of Materials Chemistry A

Volume

3

Issue/Number

15

Publication Date

1-1-2015

Document Type

Article

DOI Link

http://dx.doi.org/10.1039/c4ta07101h

Language

English

First Page

7870

Last Page

7876

WOS Identifier

WOS:000352441100026

ISSN

2050-7488

Recommended Citation

"Fabrication of layered Ti3C2 with an accordion-like structure as a potential cathode material for high performance lithium-sulfur batteries" (2015). Faculty Bibliography 2010s. 6924.
https://stars.library.ucf.edu/facultybib2010/6924