Title
Fluorene-Based Metal-Ion Sensing Probe with High Sensitivity to Zn2+ and Efficient Two-Photon Absorption
Abbreviated Journal Title
J. Phys. Chem. B
Keywords
INTRAMOLECULAR PROTON-TRANSFER; EXCITATION CROSS-SECTIONS; ONE-PHOTON; FLUORESCENT SENSORS; MACROCYCLIC LIGAND; DERIVATIVES; MICROSCOPY; ZINC; NM; PHOTOSENSITIZERS; Chemistry, Physical
Abstract
The photophysical, photochemical, two-photon absorption (2PA) and metal ion sensing properties of a new fluorene derivative (E)-1-(7-(4-(benzo[d]thiazol-2-yl)styryl)-9,9-bis(2-(2-ethoxyethoxy)ethyl)-9H-fluoren-2-yl)-3-(2-(9,10,16,17,18,19,21,22,23,24-decahydro-6H dibenzo[h,s][1,4,7,11,14,17]trioxatriazacycloicosin-20(7H)-yl)ethyl)thiourea (1) were investigated in organic and aqueous media. High sensitivity and selectivity of 1 to Zn2+ in tetrahydrofuran and a water/acetonitrile mixture were shown by both absorption and fluorescence titration. The observed complexation processes corresponded to 1:1 stoichiometry with the range of binding constants similar to(2-3) x 10(5) M-1. The degenerate 2PA spectra of 1 and 1/Zn2+ complex were obtained in the 640-900 nm spectral range with the maximum values of two-photon action cross section for ligand/metal complex similar to(90-130) GM, using a standard two-photon induced fluorescence methodology under femtosecond excitation. The nature of the 2PA bands was analyzed by quantum chemical methods and a specific dependence on metal ion binding processes was shown. Ratiometric fluorescence detection (420/650 nm) provided a good dynamic range (10(-4) to 10(-6) M) for detecting Zn2+, which along with the good photostability and 2PA properties of probe 1 makes it a good candidate in two-photon fluorescence microscopy imaging and sensing of Zn ions.
Journal Title
Journal of Physical Chemistry B
Volume
114
Issue/Number
28
Publication Date
1-1-2010
Document Type
Article
DOI Link
Language
English
First Page
9313
Last Page
9321
WOS Identifier
ISSN
1520-6106
Recommended Citation
"Fluorene-Based Metal-Ion Sensing Probe with High Sensitivity to Zn2+ and Efficient Two-Photon Absorption" (2010). Faculty Bibliography 2010s. 6990.
https://stars.library.ucf.edu/facultybib2010/6990
Comments
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