Title
Far infrared spectroscopy of carbonate minerals
Abbreviated Journal Title
Am. Miner.
Keywords
IR spectroscopy; far infrared; transmittance spectra; carbonate minerals; ACTIVE VIBRATIONS; CALCITE; SPECTRA; ARAGONITE; Geochemistry & Geophysics; Mineralogy
Abstract
This study presents far infrared spectra in the range 650-70 cm(-1) of 18 common and rare carbonate minerals. Mineral samples of known provenance are selected and physically characterized to determine the purity of the crystalline phase and their composition. The fine ground mineral powders are embedded in polyethylene pellets, and their transmittance spectra are collected with a Fourier spectrometer. The far infrared spectra of different carbonate minerals from the same structural group have well-defined similarities. Observed shifts generally manifest the mass effect of the constituent metal cations. Remarkable spectral differences occur for different carbonates in the far IR region and may serve as fingerprints for mineral identification and are more useful identifiers of carbonate species than those in any other infrared range. For some of the minerals studied here, like kutnohorite, artinite, gaylussite, and trona, no far infrared spectra to that extend (up to 70 cm(-1)) have been found in literature.
Journal Title
American Mineralogist
Volume
95
Issue/Number
10
Publication Date
1-1-2010
Document Type
Article
Language
English
First Page
1515
Last Page
1522
WOS Identifier
ISSN
0003-004X
Recommended Citation
"Far infrared spectroscopy of carbonate minerals" (2010). Faculty Bibliography 2010s. 7021.
https://stars.library.ucf.edu/facultybib2010/7021
Comments
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