Authors

G. Nootz; L. A. Padilha; L. Levina; V. Sukhovatkin; S. Webster; L. Brzozowski; E. H. Sargent; D. J. Hagan;E. W. Van Stryland

Comments

Authors: contact us about adding a copy of your work at [email protected]

Abbreviated Journal Title

Phys. Rev. B

Keywords

MULTIPLE EXCITON GENERATION; SEMICONDUCTOR NANOCRYSTALS; ELECTRONIC-STRUCTURE; EFFICIENCY; RELAXATION; Physics, Condensed Matter

Abstract

The time dynamics of the photoexcited carriers and carrier-multiplication efficiencies in PbS quantum dots (QDs) are investigated. In particular, we report on the carrier dynamics, including carrier multiplication, as a function of QD size and compare them to the bulk value. We show that the intraband 1P - > 1S decay becomes faster for smaller QDs, in agreement with the absence of a phonon bottleneck. Furthermore, as the size of the QDs decreases, the energy threshold for carrier multiplication shifts from the bulk value to higher energies. However, the energy threshold shift is smaller than the band-gap shift and, therefore, for the smallest QDs, the threshold approaches 2.35 E(g), which is close to the theoretical energy conservation limit of twice the band gap. We also show that the carrier-multiplication energy efficiency increases with decreasing QD size. By comparing to theoretical models, our results suggest that impact ionization is sufficient to explain carrier multiplication in QDs.

Journal Title

Physical Review B

Volume

83

Issue/Number

15

Publication Date

1-1-2011

Document Type

Article

Language

English

First Page

7

WOS Identifier

WOS:000289190700004

ISSN

1098-0121

Download

Share

COinS
 

Accessibility Statement

This item was created or digitized prior to April 24, 2027, or is a reproduction of legacy media created before that date. It is preserved in its original, unmodified state specifically for research, reference, or historical recordkeeping. In accordance with the ADA Title II Final Rule, the University Libraries provides accessible versions of archival materials upon request. To request an accommodation for this item, please submit an accessibility request form.