Title
Synthesis of 2-Aryl-3 Fluoralkoxy-1-Pro-penes and Some Potentially Useful Reactions of These Systems
Abstract
This report discusses research involving the fluoroalkoxylation of 2-arylprop-1-en-3-yltrimethylammonium iodides and the useful synthetic application of the adducts formed. The present work includes: 1) reactions of several 2-arylprop-1-en-3-yltrimethylammonium iodides with the sodium salt of 2,2,2-trifluoroethanol; 2) reactions of several fluoroalkoxy alcohols with 2-(4-bromophenyl)prop-1-en-3-yltrimethylammonium iodide; and 3) the oxidation of 2-(4-chlorophenyl)-3-(2,2,2-trifluoroethyoxy)-1-propene using the Lemieux/von Rudloff reagent. This report reveals the experimental conditions and procedures used as well as spectral and physical data of all new compounds synthesized. Explanation is offered for a possible mechanism for the formation of these compounds and recommendations for future research are given.
Graduation Date
1987
Semester
Summer
Advisor
Gupton, John T.
Degree
Master of Science (M.S.)
College
College of Arts and Sciences
Department
Chemistry
Degree Program
Industrial Chemistry
Format
Pages
38 p.
Language
English
Rights
Public Domain
Length of Campus-only Access
None
Access Status
Masters Thesis (Open Access)
Identifier
DP0020551
STARS Citation
Brown, Joan E., "Synthesis of 2-Aryl-3 Fluoralkoxy-1-Pro-penes and Some Potentially Useful Reactions of These Systems" (1987). Retrospective Theses and Dissertations. 5048.
https://stars.library.ucf.edu/rtd/5048