Title

Synthesis Of Secondary Amines Via N-(Benzoyloxy)Amines And Organoboranes

Abstract

A variety of primary amines (R-NH2) were converted to their corresponding N-(benzoyloxy)amines (i.e., R-NHOCOPh) under biphasic conditions in excellent yields (63-90%). The intermediate N- (benzoyloxy)amines were converted to their N-ethylamine derivatives upon reaction with triethylborane in THF in good yield (54-89%). These experiments demonstrated the similar chemistry of N-chloro- and N-(benzoyloxy)amines with organoboranes.

Publication Date

2-5-1999

Publication Title

Journal of Organic Chemistry

Volume

64

Issue

3

Number of Pages

803-806

Document Type

Article

Personal Identifier

scopus

DOI Link

https://doi.org/10.1021/jo981613l

Socpus ID

0033524874 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/0033524874

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