Title

An Efficient, Regiocontrolled Synthesis Of 5-Aryl-2-Carbethoxypyrroles From 3-Aryl-3-Chloropropeniminium Salts

Abstract

A variety of 3-aryl-3-chloropropeniminium salts react with α-amino acid esters under basic conditions to produce 2-carbethoxy-5-arylpyrroles in a regioselective manner. The overall process represents a short, efficient, and convergent synthesis of 2,5-disubstituted pyrroles, and azomethine ylides or azapentadienyl anions may be involved as intermediates. © 1992, American Chemical Society. All rights reserved.

Publication Date

9-1-1992

Publication Title

Journal of Organic Chemistry

Volume

57

Issue

20

Number of Pages

5480-5483

Document Type

Article

Identifier

scopus

Personal Identifier

scopus

DOI Link

https://doi.org/10.1021/jo00046a033

Socpus ID

0001440625 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/0001440625

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