Title

Electrophoretically Deposited Alumina As Protective Overlay For Thermal Barrier Coatings Against Cmas Degradation

Keywords

CMAS degradation; Electrophoretic deposition; Environmental degradation; Overlay barrier coating; Thermal barrier coating

Abstract

TBCs are increasingly susceptible to degradation by airborne CMAS deposits. In order to mitigate the CMAS attack, we fabricated a dense, crack-free alumina overlay for TBCs by electrophoretic deposition (EPD) technique. Overlay coatings of controlled thickness were successfully fabricated for YSZ TBCs, by EPD followed by controlled sintering at 1200 °C. YSZ with alumina overlay coatings were tested for CMAS attack at 1300 °C. Detailed examination of microstructural changes and phase evolution in CMAS tested specimens was performed by X-ray diffraction and electron microscopy. Dense alumina overlay produced by EPD was found to physically suppress the infiltration of CMAS. Furthermore, CMAS was found to crystallize into anorthite (CaAl2Si2O8) and MgAl2O4 spinel by chemically interacting with EPD α-Al2O3. A shift in CMAS glass composition to a crystallizable Al-rich glass composition promoted the formation of anorthite platelets (CaAl2Si2O8) and localized enrichment of Mg promoted the formation of MgAl2O4 spinel. EPD alumina overlay on commercial-production TBCs retained its adhesion and structural integrity after 20 cycles of 1-hour furnace thermal cycle test at 1100 °C. © 2009 Elsevier B.V. All rights reserved.

Publication Date

12-25-2009

Publication Title

Surface and Coatings Technology

Volume

204

Issue

6-7

Number of Pages

797-801

Document Type

Article

Personal Identifier

scopus

DOI Link

https://doi.org/10.1016/j.surfcoat.2009.09.055

Socpus ID

71849101610 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/71849101610

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