Title
Synthesis And Characterization Of N1-(4-Toluenesulfonyl)-N1-(9-Anthracenemethyl)Triamines
Abstract
A modular synthetic approach was developed to access triamines with varying tether lengths from commercially available aminoalkanols. Initial N-alkylation via reductive amination with anthracene-9-carbaldehyde provided the secondary amines in good yield. Subsequent ditosylation with excess TsC1 yielded the respective bis-N,O-tosylates. The tosylates were reacted with excess putrescine to give the final triamines. X-ray crystallography revealed that the polyamine tail is preferentially oriented over the shielding cone of the anthracene ring.
Publication Date
11-1-2002
Publication Title
Journal of Organic Chemistry
Volume
67
Issue
22
Number of Pages
7865-7868
Document Type
Article
Personal Identifier
scopus
DOI Link
https://doi.org/10.1021/jo020331p
Copyright Status
Unknown
Socpus ID
0036827810 (Scopus)
Source API URL
https://api.elsevier.com/content/abstract/scopus_id/0036827810
STARS Citation
Wang, Chaojie; Abboud, Khalil A.; and Phanstiel IV, Otto, "Synthesis And Characterization Of N1-(4-Toluenesulfonyl)-N1-(9-Anthracenemethyl)Triamines" (2002). Scopus Export 2000s. 2429.
https://stars.library.ucf.edu/scopus2000/2429