Title

Synthesis And Characterization Of N1-(4-Toluenesulfonyl)-N1-(9-Anthracenemethyl)Triamines

Abstract

A modular synthetic approach was developed to access triamines with varying tether lengths from commercially available aminoalkanols. Initial N-alkylation via reductive amination with anthracene-9-carbaldehyde provided the secondary amines in good yield. Subsequent ditosylation with excess TsC1 yielded the respective bis-N,O-tosylates. The tosylates were reacted with excess putrescine to give the final triamines. X-ray crystallography revealed that the polyamine tail is preferentially oriented over the shielding cone of the anthracene ring.

Publication Date

11-1-2002

Publication Title

Journal of Organic Chemistry

Volume

67

Issue

22

Number of Pages

7865-7868

Document Type

Article

Personal Identifier

scopus

DOI Link

https://doi.org/10.1021/jo020331p

Socpus ID

0036827810 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/0036827810

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