Title

Luminescence-Center-Mediated Excitation As The Dominant Er Sensitization Mechanism In Er-Doped Silicon-Rich Si O2 Films

Abstract

The structural and optical properties of erbium-doped silicon-rich silica samples containing 12 at. % of excess silicon and 0.63 at. % of erbium are studied as a function of annealing temperature in the range 600-1200°C. Indirect excitation of Er3+ ions is shown to be present for all annealing temperatures, including annealing temperatures well below 1000°C for which no silicon nanocrystals are observed. Two distinct efficient (ηtr >60%) transfer mechanisms responsible for Er3+ excitation are identified: a fast transfer process (τtr <80 ns) involving isolated luminescence centers (LCs), and a slow transfer process (τtr ∼4-100 μs) involving excitation by quantum confined excitons inside Si nanocrystals. The LC-mediated excitation is shown to be the dominant excitation mechanism for all annealing temperatures. The presence of a LC-mediated excitation process is deduced from the observation of an annealing-temperature-independent Er3+ excitation rate, a strong similarity between the LC and Er3+ excitation spectra, as well as an excellent correspondence between the observed LC-related emission intensity and the derived Er3+ excitation density for annealing temperatures in the range of 600-1000°C. The proposed interpretation provides an alternative explanation for several observations existing in the literature. © 2007 The American Physical Society.

Publication Date

11-15-2007

Publication Title

Physical Review B - Condensed Matter and Materials Physics

Volume

76

Issue

19

Number of Pages

-

Document Type

Article

Personal Identifier

scopus

DOI Link

https://doi.org/10.1103/PhysRevB.76.195419

Socpus ID

36249026533 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/36249026533

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