Title

Large Spin-State Changes In Isostructural Cyanate-And Azide-Bridged Mn 3IiiMn2Ii Single-Molecule Magnets

Abstract

We prepared three structurally related Mn3IIIMn 2II complexes that possess S ≈ 1-11 spin ground states as a result of variations in the geometry and identity of μ 2-η 1:η 1 bridging groups. These complexes function as single-molecule magnets yet demonstrate other interesting behavior such as quasi-classical magnetization hysteresis and comparable magnetization reversal barriers (Ueff). © 2010 American Chemical Society.

Publication Date

2-15-2010

Publication Title

Inorganic Chemistry

Volume

49

Issue

4

Number of Pages

1304-1306

Document Type

Article

Personal Identifier

scopus

DOI Link

https://doi.org/10.1021/ic902298y

Socpus ID

77249148420 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/77249148420

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