Title

Low Equivalent Weight Friedel-Crafts Cross-Linked Sulfonated Poly(Ether Ether Ketone)

Keywords

Benzenedimethanol; Cross-linked; Friedel-Crafts; Membrane; Polymer; SPEEK

Abstract

Poly(ether ether ketone) (PEEK) was sulfonated by electrophillic aromatic substitution to produce a highly water soluble polymer. With an equivalent weight (EW) of 381g/eq, the polymer is capable of a proton conductivity of 0.2S/cm at 80°C and 100% relative humidity (RH). High proton conductivity in polymer electrolyte membranes is a key factor for optimum hydrogen fuel cell performance. Under testing at saturating RHs, the highly sulfonated polymer absorbs water while simultaneously becoming swollen and mechanically weak. To maintain mechanical stability, a ZnCl2 catalyst was used to catalyze a Friedel-Crafts-type cross-linking using benzenedimethanol(BDM) as cross-linking agent. Although membrane thermal properties did not improve substantially, solubility was decreased and mechanical strength increased. Membranes cross-linked with 12 and 24wt.% BDM yielded polymers with equivalent weights of 395 and 416g/eq and conductivities of 0.15 and 0.14S/cm at 80°C and 100% RH, respectively, without excessive water uptake shown by the pure 96% sulfonated PEEK. Characterization of the pure and cross-linked membranes were also studied using Fourier transform infrared spectroscopy, water uptake, thermogravimetric coupled mass spectrometry and differential scanning calorimetry. Membranes were covered with platinum on carbon catalyst ink, and further characterized using linear sweep voltammetry. Behavior comparable to perfluoroalkyl sulfonate ionomers was demonstrated. © 2011 Elsevier B.V.

Publication Date

7-1-2011

Publication Title

Journal of Membrane Science

Volume

376

Issue

1-2

Number of Pages

290-301

Document Type

Article

Personal Identifier

scopus

DOI Link

https://doi.org/10.1016/j.memsci.2011.04.039

Socpus ID

79957571731 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/79957571731

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