Title
Cationic Mn4 Single-Molecule Magnet With A Sterically Isolated Core
Abstract
The synthesis, structure, and magnetic properties of a ligand-modified Mn4 dicubane single-molecule magnet (SMM), [Mn4(Bet) 4(mdea)2(mdeaH)2](BPh4) 4, are presented, where the cationic SMM units are significantly separated from neighboring molecules in the crystal lattice. There are no cocrystallized solvate molecules, making it an ideal candidate for single-crystal magnetization hysteresis and high-frequency electron paramagnetic resonance studies. Increased control over intermolecular interactions in such materials is a crucial factor in the future application of SMMs. © 2011 American Chemical Society.
Publication Date
8-15-2011
Publication Title
Inorganic Chemistry
Volume
50
Issue
16
Number of Pages
7367-7369
Document Type
Article
Personal Identifier
scopus
DOI Link
https://doi.org/10.1021/ic201017r
Copyright Status
Unknown
Socpus ID
80051479239 (Scopus)
Source API URL
https://api.elsevier.com/content/abstract/scopus_id/80051479239
STARS Citation
Heroux, Katie J.; Quddusi, Hajrah M.; Liu, Junjie; O'Brien, James R.; and Nakano, Motohiro, "Cationic Mn4 Single-Molecule Magnet With A Sterically Isolated Core" (2011). Scopus Export 2010-2014. 2690.
https://stars.library.ucf.edu/scopus2010/2690