Title

Co-Assembly Of Zn(Sph) 2 And Organic Linkers Into Helical And Zig-Zag Polymer Chains

Keywords

Coordination polymers; Organic linkers; Single helicate; Zig-zag structure

Abstract

Two novel one-dimensional coordination polymers, single helicate [Zn(SPh) 2(TPyTA)(EG)] n (EG=ethylene glycol) (1) and zig-zag structure [Zn(SPh) 2(BPyVB)] n (2), were synthesized under solvothermal conditions at 150 °C or room temperature by the co-assembly of Zn(SPh) 2 and organic linkers such as 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPyTA) and 1,3-bis(trans-4-pyridylvinyl) benzene (BPyVB). X-ray crystallography study reveals that both polymers 1 and 2 crystallize in space group P2 1/c of the monoclinic system. The solid-state UV-vis absorption spectra show that 1 and 2 have maxium absorption onsets at 400 nm and 420 nm, respectively. TGA analysis indicates that 1 and 2 are stable up to 110 °C and 210 °C. © 2012 Elsevier Inc.

Publication Date

7-1-2012

Publication Title

Journal of Solid State Chemistry

Volume

191

Number of Pages

283-286

Document Type

Article

Personal Identifier

scopus

DOI Link

https://doi.org/10.1016/j.jssc.2012.03.044

Socpus ID

84862216835 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/84862216835

This document is currently not available here.

Share

COinS