Title

Effect Of Sc Addition On The Microstructure And Mechanical Properties Of As-Atomized And Extruded Al-20Si Alloys

Keywords

Atom probe tomography; Diffusion; Grain boundary; Polycrystalline film; Triple junction

Abstract

With the development of nanotechnologies, the number of industrial processes dealing with the production of nanostructures or nano-objects is in constant progress (microelectronics, metallurgy⋯). Thus, knowledge of atom mobility and the understanding of atom redistribution in nano-objects and during their fabrication have become subjects of increasing importance, since they are key parameters to control nano-fabrication. Especially, today's materials can be both composed of nano-objects as clusters or decorated defects⋯, and contain a large number of interfaces as in nanometer-thick film stacking and buried nano-wires or nano-islands. Atom redistribution in this type of materials is quite complex due to the combination of different effects, such as composition and stress, and is still not very well known due to experimental issues. For example, it has been shown that atomic transport in nanocrystalline layers can be several orders of magnitude faster than in microcrystalline layers, though the reason for this mobility increase is still under debate. Effective diffusion in nanocrystalline layers is expected to be highly dependent on interface and grain boundary (GB) diffusion, as well as triple junction diffusion. However, experimental measurements of diffusion coefficients in nano-grains, nano-grain boundaries, triple junctions, and interfaces, as well as investigations concerning diffusion mechanisms, and defect formation and mobility in these different diffusion paths are today still needed, in order to give a complete picture of nano-diffusion and nano-size effects upon atom transport. In this paper, we present recent studies dealing with diffusion in nano-crystalline materials using original simulations combined with usual 1D composition profile measurements, or using the particular abilities of atom probe tomography (APT) to experimentally characterize interfaces. We present techniques allowing for the simultaneous measurement of grain and GB diffusion coefficients in polycrystals, as well as the measurement of nano-grain lattice diffusion and triple junction diffusion. We also show that laserassisted APT microscopy is the ideal tool to study interface diffusion and nano-diffusion in nanostructures, since it allows the determination of 1D, 2D and 3D atomic distributions that can be analyzed using diffusion analytical solutions or numerical simulation. © 2012 Trans Tech Publications, Switzerland.

Publication Date

3-15-2012

Publication Title

Materials Letters

Volume

71

Number of Pages

164-167

Document Type

Article

Personal Identifier

scopus

DOI Link

https://doi.org/10.1016/j.matlet.2011.12.050

Socpus ID

84862804810 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/84862804810

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