Title
Trends In The Binding Strength Of Surface Species On Nanoparticles: How Does The Adsorption Energy Scale With The Particle Size?
Keywords
adsorption calorimetry; binding strength; metal nanoparticles; oxygen; palladium
Abstract
The binding energy of oxygen on Pd nanoparticles was measured by a direct calorimetric method as a function of the particle size. The reduced dimensionality of the Pd substrate results in two counteracting trends: an increase of the Pd-O binding strength due to a change of the local configuration of the adsorption site and a strong decrease of the Pd-O bonding due to the reduction of the cluster size. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Publication Date
5-3-2013
Publication Title
Angewandte Chemie - International Edition
Volume
52
Issue
19
Number of Pages
5175-5179
Document Type
Article
Personal Identifier
scopus
DOI Link
https://doi.org/10.1002/anie.201209476
Copyright Status
Unknown
Socpus ID
84877710994 (Scopus)
Source API URL
https://api.elsevier.com/content/abstract/scopus_id/84877710994
STARS Citation
Peter, Matthias; Florescamacho, Jose Manuel; Adamovski, Serguey; Ono, Luis K.; and Dostert, Karl Heinz, "Trends In The Binding Strength Of Surface Species On Nanoparticles: How Does The Adsorption Energy Scale With The Particle Size?" (2013). Scopus Export 2010-2014. 6959.
https://stars.library.ucf.edu/scopus2010/6959