Title

Comparison Of Shaking Versus Baking: Further Understanding The Energetics Of A Mechanochemical Reaction

Abstract

Using a mechanically driven Diels-Alder reaction we were able to characterize the chemical energetics of a SPEX 8000M mixer/mill. Our results demonstrate that the conditions produced by this type of mill are similar to those produced when performing the same reaction at 90 °C in solution. Discrete element models and in situ temperature logging were used to analyse the energetics of this system. These models indicate that the yields obtained using a SPEX 8000M mill are best correlated to the velocity of the media and number of non-zero force collisions. © 2014 The Royal Society of Chemistry.

Publication Date

1-1-2014

Publication Title

Green Chemistry

Volume

16

Issue

3

Number of Pages

1628-1632

Document Type

Article

Personal Identifier

scopus

DOI Link

https://doi.org/10.1039/c3gc41496e

Socpus ID

84894632752 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/84894632752

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