Title
Facile Incorporation Of Pd(Pph3)2Hal Substituents Into Polymethines, Merocyanines, And Perylene Diimides As A Means Of Suppressing Intermolecular Interactions
Abstract
Compounds with polarizable π systems that are susceptible to attack with nucleophiles at C-Hal (Hal = Cl, Br) bonds react with Pd(PPh3)4 to yield net oxidative addition. X-ray structures show that the resulting Pd(PPh3)2Hal groups greatly reduce intermolecular π-π interactions. The Pd-functionalized dyes generally exhibit solution-like absorption spectra in films, whereas their Hal analogues exhibit features attributable to aggregation.
Publication Date
8-17-2016
Publication Title
Journal of the American Chemical Society
Volume
138
Issue
32
Number of Pages
10112-10115
Document Type
Article
Personal Identifier
scopus
DOI Link
https://doi.org/10.1021/jacs.6b06361
Copyright Status
Unknown
Socpus ID
84983466444 (Scopus)
Source API URL
https://api.elsevier.com/content/abstract/scopus_id/84983466444
STARS Citation
Davydenko, Iryna; Barlow, Stephen; Sharma, Rajesh; Benis, Sepehr; and Simon, Janos, "Facile Incorporation Of Pd(Pph3)2Hal Substituents Into Polymethines, Merocyanines, And Perylene Diimides As A Means Of Suppressing Intermolecular Interactions" (2016). Scopus Export 2015-2019. 2519.
https://stars.library.ucf.edu/scopus2015/2519