Facile Incorporation Of Pd(Pph3)2Hal Substituents Into Polymethines, Merocyanines, And Perylene Diimides As A Means Of Suppressing Intermolecular Interactions

Creator

Iryna Davydenko, Georgia Institute of Technology
Stephen Barlow, Georgia Institute of Technology
Rajesh Sharma, University of Central Florida
Sepehr Benis, University of Central Florida
Janos Simon, Georgia Institute of Technology

Abstract

Compounds with polarizable π systems that are susceptible to attack with nucleophiles at C-Hal (Hal = Cl, Br) bonds react with Pd(PPh3)4 to yield net oxidative addition. X-ray structures show that the resulting Pd(PPh3)2Hal groups greatly reduce intermolecular π-π interactions. The Pd-functionalized dyes generally exhibit solution-like absorption spectra in films, whereas their Hal analogues exhibit features attributable to aggregation.

Publication Date

8-17-2016

Publication Title

Journal of the American Chemical Society

Volume

138

Issue

32

Number of Pages

10112-10115

Document Type

Article

Personal Identifier

scopus

DOI Link

https://doi.org/10.1021/jacs.6b06361

Copyright Status

Unknown

Socpus ID

84983466444 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/84983466444

STARS Citation

Davydenko, Iryna; Barlow, Stephen; Sharma, Rajesh; Benis, Sepehr; and Simon, Janos, "Facile Incorporation Of Pd(Pph3)2Hal Substituents Into Polymethines, Merocyanines, And Perylene Diimides As A Means Of Suppressing Intermolecular Interactions" (2016). Scopus Export 2015-2019. 2519.
https://stars.library.ucf.edu/scopus2015/2519