From Pink To Blue And Back To Pink Again: Changing The Co(Ii) Ligation In A Two-Dimensional Coordination Network Upon Desolvation

Creator

Diana Chisca, Institute of Applied Physics Academy of Sciences of Moldava
Lilia Croitor, Institute of Applied Physics Academy of Sciences of Moldava
Eduard B. Coropceanu, Academy of Sciences of Moldova
Oleg Petuhov, Academy of Sciences of Moldova
Svetlana G. Baca, Institute of Applied Physics Academy of Sciences of Moldava

Abstract

Heating of a pink two-dimensional Co(ii) coordination network {[Co2(μ2-OH2)(bdc)2(S-nia)2(H2O)(dmf)]·2(dmf)·(H2O)}n (1) built from 1,4-benzenedicarboxylic acid (H2bdc) residues and thionicotinamide (S-nia) ligands initiates a single-crystal-to-single-crystal transition accompanied by removal of both coordinated and co-crystallized solvents. In the dry blue form, [Co(bdc)(S-nia)]n (dry-1), the Co(ii) centers changed from an octahedral to a square pyramidal configuration.

Publication Date

1-1-2016

Publication Title

CrystEngComm

Volume

18

Issue

3

Number of Pages

384-389

Document Type

Article

Personal Identifier

scopus

DOI Link

https://doi.org/10.1039/c5ce01581b

Copyright Status

Unknown

Socpus ID

84954049950 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/84954049950

STARS Citation

Chisca, Diana; Croitor, Lilia; Coropceanu, Eduard B.; Petuhov, Oleg; and Baca, Svetlana G., "From Pink To Blue And Back To Pink Again: Changing The Co(Ii) Ligation In A Two-Dimensional Coordination Network Upon Desolvation" (2016). Scopus Export 2015-2019. 3190.
https://stars.library.ucf.edu/scopus2015/3190