Title
From Pink To Blue And Back To Pink Again: Changing The Co(Ii) Ligation In A Two-Dimensional Coordination Network Upon Desolvation
Abstract
Heating of a pink two-dimensional Co(ii) coordination network {[Co2(μ2-OH2)(bdc)2(S-nia)2(H2O)(dmf)]·2(dmf)·(H2O)}n (1) built from 1,4-benzenedicarboxylic acid (H2bdc) residues and thionicotinamide (S-nia) ligands initiates a single-crystal-to-single-crystal transition accompanied by removal of both coordinated and co-crystallized solvents. In the dry blue form, [Co(bdc)(S-nia)]n (dry-1), the Co(ii) centers changed from an octahedral to a square pyramidal configuration.
Publication Date
1-1-2016
Publication Title
CrystEngComm
Volume
18
Issue
3
Number of Pages
384-389
Document Type
Article
Personal Identifier
scopus
DOI Link
https://doi.org/10.1039/c5ce01581b
Copyright Status
Unknown
Socpus ID
84954049950 (Scopus)
Source API URL
https://api.elsevier.com/content/abstract/scopus_id/84954049950
STARS Citation
Chisca, Diana; Croitor, Lilia; Coropceanu, Eduard B.; Petuhov, Oleg; and Baca, Svetlana G., "From Pink To Blue And Back To Pink Again: Changing The Co(Ii) Ligation In A Two-Dimensional Coordination Network Upon Desolvation" (2016). Scopus Export 2015-2019. 3190.
https://stars.library.ucf.edu/scopus2015/3190