Ultrathin High Surface Area Nickel Boride (NiXB) Nanosheets As Highly Efficient Electrocatalyst For Oxygen Evolution

Keywords

hydrogen evolution; nickel boride; oxygen evolution; water oxidation; water splitting; XAFS

Abstract

The overriding obstacle to mass production of hydrogen from water as the premium fuel for powering our planet is the frustratingly slow kinetics of the oxygen evolution reaction (OER). Additionally, inadequate understanding of the key barriers of the OER is a hindrance to insightful design of advanced OER catalysts. This study presents ultrathin amorphous high-surface area nickel boride (NixB) nanosheets as a low-cost, very efficient and stable catalyst for the OER for electrochemical water splitting. The catalyst affords 10 mA cm−2 at 0.38 V overpotential during OER in 1.0 m KOH, reducing to only 0.28 V at 20 mA cm−2 when supported on nickel foam, which ranks it among the best reported nonprecious catalysts for oxygen evolution. Operando X-ray absorption fine-structure spectroscopy measurements reveal prevalence of NiOOH, as well as Ni-B under OER conditions, owing to a Ni-B core@nickel oxyhydroxide shell (Ni-B@NiOxH) structure, and increase in disorder of the NiOxH layer, thus revealing important insight into the transient states of the catalyst during oxygen evolution.

Publication Date

9-6-2017

Publication Title

Advanced Energy Materials

Volume

7

Issue

17

Document Type

Article

Personal Identifier

scopus

DOI Link

https://doi.org/10.1002/aenm.201700381

Socpus ID

85019078832 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/85019078832

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