Determining The Liquid Light Scattering Cross Section And Depolarization Spectra Using Polarized Resonance Synchronous Spectroscopy

Abstract

Rayleigh scattering is a universal material property because all materials have nonzero polarizability. Reliable quantification of the material light scattering cross section in the liquid phase and its depolarization spectra is, however, challenging due to a host of sample and instrument issues. Using the recently developed polarized resonance synchronous spectroscopic method, we reported the light scattering cross section and depolarization spectra measured for a total of 29 liquids including water, methanol, ethanol, 1-propanol, 1-butanol, dimethylformamide, carbon disulfide, dimethyl sulfoxide, hexane and two hexane isomers (3-methylpentane and 2,3-dimethylbutane), tetrahydrofuran, cyclohexane, acetonitrile, pyridine, chloromethanes including di-, tri, tetrachloromethane, acetone, benzene and eight benzene derivatives (toluene, fluorobenzene, 1,2-, 1,3-, and 1,4-difluorobenzene, chlorobenzene, 1,2- and 1,3-dichlorobenzene, and nitrobenzene). The solvent light scattering depolarization is wavelength-independent for the model solvents, and it varies from 0.023 ± 0.011 for CCl4 to 0.619 ± 0.022 for nitrobenzene. The light scattering cross-section spectra can be approximated with the function of σ(λ) = αλ-4 with the α value varying from 7.2 ± 0.2 × 10-45 cm6 for water to a maximum of 8.5 ± 0.6 × 10-43 cm6 for nitrobenzene. Structural isomerization has no significant effect on either the depolarization or the scattering cross sections for both hexanes and difluorobenzene isomers. This work represents the most comprehensive experimental study on liquid light scattering features. The insight from this work should be important for understanding the correlation between the material structure and optical properties. The described method can be readily implemented by researchers with access to conventional spectrofluorometers equipped with excitation and detection polarizers.

Publication Date

12-5-2017

Publication Title

Analytical Chemistry

Volume

89

Issue

23

Number of Pages

12705-12712

Document Type

Article

Personal Identifier

scopus

DOI Link

https://doi.org/10.1021/acs.analchem.7b02721

Socpus ID

85037534202 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/85037534202

This document is currently not available here.

Share

COinS