Structural Stability Of N-Alkyl-Functionalized Titanium Metal-Organic Frameworks In Aqueous And Humid Environments

Keywords

functional materials; metal-organic frameworks; photocatalysis; porous coordination polymers; porous materials; water adsorption

Abstract

We demonstrate that the highly photoredox active metal-organic framework (MOF) MIL-125-NHCyp exhibits crystalline and porosity stability in humid environments for more than 30 days as well as increased hydrophobicity compared to the unfunctionalized framework. This improved stability, in synergy with its high photocatalytic activity, makes this MOF a very promising candidate for large-scale applications in CO2 photoreduction.

Publication Date

12-27-2017

Publication Title

ACS Applied Materials and Interfaces

Volume

9

Issue

51

Number of Pages

44529-44533

Document Type

Article

Personal Identifier

scopus

DOI Link

https://doi.org/10.1021/acsami.7b15045

Socpus ID

85038634359 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/85038634359

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