Apically Dominant Mechanism For Improving Catalytic Activities Of N-Doped Carbon Nanotube Arrays In Rechargeable Zinc–Air Battery

Keywords

apically dominant mechanism; electrocatalysts; N-doped carbon nanotubes; PGM-free; zinc–air batteries

Abstract

The oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) in zinc–air batteries (ZABs) require highly efficient, cost-effective, and stable electrocatalysts as alternatives to high cost and low poison resistant platinum group metals (PGM) catalysts. Although nitrogen-doped carbon nanotube (NCNT) arrays are now capable of catalyzing ORR efficiently, their hydrophobic surface and base-growth mode are found to limit the catalytic performance in the practical ZABs. Here, the concept of an apically dominant mechanism in improving the catalytic performance of NCNT by precisely encapsulating CoNi nanoparticles (NPs) within the apical domain of NCNT on the Ni foam (denoted as CoNi@NCNT/NF) is demonstrated. The CoNi@NCNT/NF exhibits a more excellent catalytic performance toward both ORR and OER than that of traditional NCNT derived from the base-growth method. The ZAB coin cell using CoNi@NCNT/NF as an air electrode shows a peak power density of 127 mW cm−2 with an energy density of 845 Wh kgZn−1 and rechargeability over 90 h, which outperforms the performance of PGM catalysts. Density functional theory calculations reveal that the ORR catalytic performance of the CoNi@NCNT/NF is mainly attributed to the synergetic contributions from NCNT and the apical active sites on NCNT near to CoNi NPs.

Publication Date

7-16-2018

Publication Title

Advanced Energy Materials

Volume

8

Issue

20

Document Type

Article

Personal Identifier

scopus

DOI Link

https://doi.org/10.1002/aenm.201800480

Socpus ID

85045408300 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/85045408300

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