Title

Nickel Sulfide Freestanding Holey Films As Air-Breathing Electrodes For Flexible Zn-Air Batteries

Abstract

In this work, a combination of bottom-up electrochemical deposition and top-down electrochemical etching strategies followed by a subsequent sulfuration treatment was employed to rationally synthesize a nickel sulfide (NiSx) freestanding holey film (FHF). Owing to the holey structure along with the optimal electrochemically active surface area and active sites, the as-prepared NiSx FHF showed an impressive bifunctional electrocatalytic performance toward both oxygen evolution and reduction reactions. The holey and freestanding features provide the NiSx FHF with promising characteristics to be used as an ideal air-breathing cathode in flexible Zn-air batteries (ZABs). As a proof-of-concept, the rationally designed NiSx FHF achieved remarkable rechargeability and flexibility in a ZAB configuration.

Publication Date

6-7-2018

Publication Title

Journal of Physical Chemistry Letters

Volume

9

Issue

11

Number of Pages

2746-2750

Document Type

Article

Personal Identifier

scopus

DOI Link

https://doi.org/10.1021/acs.jpclett.8b00925

Socpus ID

85046947177 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/85046947177

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