Vacnt, buckypaper, pdc, anisotropic, nanocomposite coatings
Ceramics have a number of applications as coating material due to their high hardness, wear and corrosion resistance, and the ability to withstand high temperatures. Critical to the success of these materials is the effective heat transfer through a material to allow for heat diffusion or effective cooling, which is often limited by the low thermal conductivity of many ceramic materials. To meet the challenge of improving the thermal conductivity of ceramics without lowering their performance envelope, carbon nanotubes were selected to improve the mechanical properties and thermal dispersion ability due to its excellent mechanical properties and high thermal conductivity in axial direction. However, the enhancements are far lower than expectation resulting from limited carbon nanotube content in ceramic matrix composites and the lack of alignment. These problems can be overcome if ceramic coatings are reinforced by carbon nanotubes with good dispersion and alignment. In this study, the well-dispersed and aligned carbon nanotubes preforms were achieved in the form of vertically aligned carbon nanotubes (VACNTs) and Buckypaper. Polymer derived ceramic (PDC) was selected as the matrix to fabricate carbon nanotube reinforced ceramic nanocomposites through resin curing and pyrolysis. The SEM images indicates the alignment of carbon nanotubes in the PDC nanocomposites. The mechanical and thermal properties of the PDC nanocomposites were characterized through Vickers hardness measurement and Thermogravimetric Analysis. The ideal anisotropic properties of nanocomposites were confirmed by estimating the electrical conductivity in two orthogonal directions.
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Master of Science in Mechanical Engineering (M.S.M.E.)
College of Engineering and Computer Science
Mechanical and Aerospace Engineering
Mechanical Engineering; Mechanical Systems Track
Length of Campus-only Access
Masters Thesis (Open Access)
Dissertations, Academic -- Engineering and Computer Science; Engineering and Computer Science -- Dissertations, Academic
Yang, Hongjiang, "Synthesis, Processing and Characterization of Polymer Derived Ceramic Nanocomposite Coating Reinforced with Carbon Nanotube Preforms" (2014). Electronic Theses and Dissertations. 4757.